Packing and compositional disorder with MoO2 Cl2 (OPMePh2)2, MoOCl3 (OPMePh2)2 and MoCl4 (OPMePh2)2 as assessed by single crystal X-ray diffraction
Document Type
Article
Publication Date
1-10-2003
Department
Department of Chemistry
Abstract
The structures as determined by single crystal X-ray determinations of MoO2Cl2(OPMePh2)2 and various mixtures of MoO2Cl2(OPMePh2)2 (A), MoOCl3(OPMePh2)2 (B) and MoCl4(OPMePh2)2 (C) specifically in ratios 40.2/59.8; 30.8/69.2; 14/86; 4/96 in A/B, 100% B and 82/18 in B/C are reported. The structural data illustrate that both compositional and packing disorder afford mechanisms by which apparent long and different Mo-O bond distances can be obtained.
Publication Title
Inorganica Chimica Acta
Recommended Citation
Fronczek, F.,
Luck, R.,
&
Wang, G.
(2003).
Packing and compositional disorder with MoO2 Cl2 (OPMePh2)2, MoOCl3 (OPMePh2)2 and MoCl4 (OPMePh2)2 as assessed by single crystal X-ray diffraction.
Inorganica Chimica Acta,
342, 247-254.
http://doi.org/10.1016/S0020-1693(02)01157-X
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/7279
