Application of an isothermal, three-phase catalytic reactor model to predict unsteady-state fixed-bed performance
Document Type
Article
Publication Date
1-15-2003
Abstract
CatReac, a three-phase catalytic mathematical model, was developed for analysis and optimization of the volatile reactor assembly used in International Space Station water processor. This wet oxidation process is used to remove low molecular weight contaminants such as acetic acid, acetone, ethanol, 1-propanol, 2-propanol, and propionic acid, which are not removed by the other treatment processes. The Langmuir-Hinshelwood (Hinshelwood, C. N. The Kinetics of Chemical Change in Gaseous Systems, 3rd ed.; Oxford: London, 1933; pp 301-347) isothermal adsorption expression was successfully used to describe the reaction kinetics of compounds on the catalyst surface for the compounds mentioned above. Small-column experiments combined with the use of the Arrhenius equation were successfully used to predict the Langmuir-Hinshelwood parameters under different temperatures for a temperature range from 93 to 149 °C. Full-scale and small-column experiments were successfully used to validate the model predictions for unsteady-state fixed-bed operations.
Publication Title
Environmental Science and Technology
Recommended Citation
Yang, J.,
Hand, D.,
Hokanson, D.,
&
Crittenden, J.
(2003).
Application of an isothermal, three-phase catalytic reactor model to predict unsteady-state fixed-bed performance.
Environmental Science and Technology,
37(2), 428-436.
http://doi.org/10.1021/es025846c
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/7943