PEGylated Dmoc phosphoramidites for sensitive oligodeoxynucleotide synthesis

Document Type

Article

Publication Date

10-31-2023

Department

Department of Chemistry; Health Research Institute

Abstract

Sensitive oligodeoxynucleotides (ODNs) can be synthesized using Dmoc phosphoramidites, but only short ODNs were demonstrated. Here, we report the synthesis of much longer ODNs, which was made possible by the use of PEGylated Dmoc (pDmoc) phosphoramidites. The longer ODNs synthesized include those containing the sensitive 4acC epigenetic modification recently discovered in nature.

Publication Title

Organic and Biomolecular Chemistry

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