Expanding molecular transition metal cubane clusters of the form [M4 (μ3 -O)4 ]12+: Syntheses, spectroscopic and structural characterizations of molecules M4 (μ3 -O)4 (O2 P(Bn)2 )4 (O4), M = V V and WV
Document Type
Article
Publication Date
11-21-2011
Department
Department of Chemistry
Abstract
Oxidizing the trimer V3(μ3-O)(O 2)(μ2-O2P(Bn)2) 6(H2O) in the presence of excess tBuOOH results in V4(μ3-O)4(μ2-O 2P(Bn)2)4(O4) and heating W(CO) 6 and bis(benzyl)phosphinic acid in 1:1 EtOH/THF at 120 °C produces W4(μ3-O)4(μ2-O 2P(Bn)2)4(O4).
Publication Title
Dalton Transactions
Recommended Citation
Maass, J.,
Chen, Z.,
Zeller, M.,
&
Luck, R.
(2011).
Expanding molecular transition metal cubane clusters of the form [M4 (μ3 -O)4 ]12+: Syntheses, spectroscopic and structural characterizations of molecules M4 (μ3 -O)4 (O2 P(Bn)2 )4 (O4), M = V V and WV.
Dalton Transactions,
40(43), 11356-11358.
http://doi.org/10.1039/c1dt11375e
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/8496