Synthesis of cyclic allyl vinyl ethers using Pt(II)-catalyzed isomerization of oxo-alkynes
Document Type
Article
Publication Date
3-28-2009
Abstract
Several alkynyl epoxides and one alkynyl allyl alcohol were isomerized to cyclic allyl vinyl ethers (3,4-dihydro-2H-1,4-oxazines) using PtCl2 as the catalyst. Three of these allyl vinyl ethers were converted to 2-hydroxymorpholine derivatives by hydrolysis and two were converted to piperidine derivatives by thermal Claisen rearrangement. © 2009 Elsevier Ltd. All rights reserved.
Publication Title
Tetrahedron
Recommended Citation
Wang, Z.,
Lin, X.,
Luck, R.,
Gibbons, G.,
&
Fang, S.
(2009).
Synthesis of cyclic allyl vinyl ethers using Pt(II)-catalyzed isomerization of oxo-alkynes.
Tetrahedron,
65(13), 2643-2648.
http://doi.org/10.1016/j.tet.2009.01.065
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/7150