"Surfactant mediated optical properties of cytosine capped CdSe quantum" by Prashant K. Sharma, Ranu K. Dutta et al.
 

Surfactant mediated optical properties of cytosine capped CdSe quantum dots

Document Type

Article

Publication Date

5-31-2010

Abstract

This letter demonstrates the use of one of the nucleobases, 'cytosine' as a new capping agent in controlling the size of the nanoparticles. A size dependent blue shift in optical absorption with enhanced luminescence is observed. Since the calculated density of states do not show any change in the band gap of as-prepared quantum dots after capping, the observed blue shift of the absorption peak can solely be attributed to the so-called size-effect whereas the enhancement in luminescence to surfactant mediated defect passivation. It is expected that the observed properties of the cytosine capped CdSe quantum dots would facilitate a better bio-compatibility of tailor-made nanoparticles for bio-imaging applications. © 2010 Elsevier B.V. All rights reserved.

Publication Title

Materials Letters

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