13C chemical shielding anisotropy in the solid phases of CH313CN
Document Type
Article
Publication Date
4-12-1996
Department
Department of Physics
Abstract
The principal elements of the axially symmetric nitrile 13C chemical shift tensor, and the C≡N bond distance of solid CH3CN have been determined from both static and sample spinning NMR experiments at 78 and 140 K. The spectra show no significant differences between the α and β forms of the solid though a large temperature coefficient is observed for both the isotropic chemical shift, σ̄, and the 14N nuclear electric quadrupole interactions as seen through the carbon-nitrogen dipole interaction.
Publication Title
Chemical Physics Letters
Recommended Citation
Šepa, J.,
Gorte, R.,
Suits, B.,
&
White, D.
(1996).
13C chemical shielding anisotropy in the solid phases of CH313CN.
Chemical Physics Letters,
252(3-4), 281-286.
http://doi.org/10.1016/0009-2614(96)00156-X
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/5226
