Malonic ester derivatives of s‐Triazine

Authors

C. Fredric Reynolds, Michigan Technological University
Robert Berner, Michigan Technological University
William Boutwell, Michigan Technological University

Document Type

Article

Publication Date

1-1-1972

Department

Department of Chemistry; Department of Chemical Engineering

Abstract

Reaction of cyanuric chloride with solutions of sodium diethyl malonate led to three products, 2,4,6‐tris(dicarbethoxymethylene)hexahydro‐s‐triazine, 2,4‐bis(dicarbethoxymethylene)‐6‐oxohexahydro‐s‐triazine, and 2‐dicarbethoxymethylene‐4,6‐dioxohexahydro‐s‐triazine. The preferred structures (IV,V,VI) are stabilized by chelated N‐H‐O protons in six membered rings. The assignment of structures was made on the basis of ir, nmr, uv and mass spectral data.

Publisher's Statement

Copyright © 1972 Journal of Heterocyclic Chemistry. Publisher’s version of record: https://doi.org/10.1002/jhet.5570090508

Publication Title

Journal of Heterocyclic Chemistry

Recommended Citation

Fredric Reynolds, C., Berner, R., & Boutwell, W. (1972). Malonic ester derivatives of s‐Triazine. Journal of Heterocyclic Chemistry, 9(5), 1009-1011. http://doi.org/10.1002/jhet.5570090508
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/3729