A two-dimensional, hydrogen-bond-cross-linked molybdenum(VI) network polymer with catalytic activity
Document Type
Article
Publication Date
3-2007
Department
Department of Chemistry
Abstract
The new hybrid inorganic-organic polymer [MoO2Cl 2(H2O)2]·(H2dipy-pra)Cl 2 (1), where dipy-pra = 1,3-bis(4-pyridyl)propane, has been synthesized and crystallographically characterized. MoO2Cl 2(H2O)2 and the [H2dipy-pra] 2+ cation are cross-linked by Mo-H2O⋯O and H 2dipy-pra⋯Cl hydrogen bonds to form a two-dimensional layer structure. Complex 1 is an efficient catalyst, with H2O2 as the oxygen-source oxidant and NaHCO3 as the cocatalyst, in the epoxidation of olefinic compounds under ambient conditions.
Publication Title
European Journal of Inorganic Chemistry
Recommended Citation
Luan, Y.,
Wang, G.,
Luck, R.,
&
Yang, M.
(2007).
A two-dimensional, hydrogen-bond-cross-linked molybdenum(VI) network polymer with catalytic activity.
European Journal of Inorganic Chemistry,
2007(9), 1215-1218.
http://doi.org/10.1002/ejic.200601054
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/3598