Structural transition and chemical reactivity of atomic carbon chains

Document Type

Article

Publication Date

5-30-2023

Abstract

The sp-hybridized carbon chain (carbyne) is a representative 1D atomic material, whose bonding structure and chemical reactivity have remained a mystery for a century. Here, we report the unexpected alternating bond orders of 1.4 and 2.6 for the most stable carbon chain and the diffuse reflectance infrared Fourier-transform spectroscopy (DRIFTS) detection of the temperature-dependent reversible change of the bond order alternation. Moreover, we revealed its reactivities with O, H, and CO at temperatures up to 600 °C and created an end-group-protection strategy to stabilize it. These observations open a new door to the chemistry of atomic materials.

Publication Title

Chemical communications (Cambridge, England)

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