Hydrogen-bond-supported 3D networks: Two different polymeric structures featuring chlorine atoms as ligands and as anions and investigations as epoxide catalysts

Document Type

Article

Publication Date

12-1-2008

Abstract

Two novel hydrogen-bonded network polymers, [MoO2Cl 2-(H2O)2]2[4,4′-H 2bipy]2+·2Cl- (1) and [MoO 2Cl4]2-[4,4′-H2-bipy] 2+ (2) [bipy = bipyridine] contained different three-dimensional NH···Cl hydrogen-bonded arrangements resulting in different polymeric structures; complex 1 or 2 as catalytic precursor, H 2O2 as a source of oxygen and NaHCO3 as cocatalyst showed great efficiency for the epoxidation of olefinic compounds under ambient conditions. Copyright © 2008 The Chemical Society of Japan.

Publication Title

Chemistry Letters

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