In Situ Growth of CuBi2O4/Bi2O3 Z-Scheme Heterostructures for Bifunctional Photocatalytic Applications
Document Type
Article
Publication Date
6-11-2024
Department
Department of Physics
Abstract
In this study, we present an in situ solvothermal approach for synthesizing a highly efficient bifunctional CuBi2O4/Bi2O3 composite catalyst for applications in H2 production and the removal of organic pollutants. Various characterization techniques, including XRD, UV-vis DRS, SEM, TEM, and EIS, were used to characterize the prepared catalyst. Density functional theory calculations confirmed a Z-scheme mechanism, revealing the charge transfer mechanism from the Bi2O3 surface to the CuBi2O4 surface. The composite exhibited a photocurrent of 2.83 × 104 A/cm2 and a hydrogen production rate of 526 μmolg-1h-1 under natural sunlight. Moreover, the catalyst demonstrated efficient degradation of RhB up to 58% in 120 min under 50 W LED illumination. Additionally, multiple recycling tests confirmed its high stability and recyclability, making it a promising candidate for various applications in the field of photocatalysis.
Publication Title
Langmuir
Recommended Citation
Mondal, S.,
Patra, L.,
Ilanchezhiyan, P.,
Neppolian, B.,
Pandey, R.,
&
Ganesh, V.
(2024).
In Situ Growth of CuBi2O4/Bi2O3 Z-Scheme Heterostructures for Bifunctional Photocatalytic Applications.
Langmuir.
http://doi.org/10.1021/acs.langmuir.4c00589
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p2/846