Experimental and theoretical study of bound and quasibound states of Ce < sup> -
Document Type
Article
Publication Date
9-21-2011
Abstract
The negative ion of cerium is investigated experimentally with tunable infrared laser photodetachment spectroscopy and theoretically with relativistic configuration interaction in the continuum formalism. The relative cross section for neutral atom production is measured with a crossed ion-beam-laser-beam apparatus over the photon energy range of 0.54-0.75 eV. A rich resonance spectrum is revealed near the threshold with, at least, 12 peaks observed due to transitions from bound states of Ce- to either bound or quasibound excited states of the negative ion. Theoretical calculations of the photodetachment cross sections enable identification of the transitions responsible for the measured peaks. Two of the peaks are due to electric dipole-allowed bound-bound transitions in Ce-, making cerium only the second atomic negative ion that has been demonstrated to support multiple bound states of opposite parity. In addition, combining the experimental data with the theoretical analysis determines the electron affinity of cerium to be 0.628(10) eV and the fine structure splitting of the ground state of Ce - (4H7/2-4H9/2) to be 0.097 75(4) eV. © 2011 American Physical Society.
Publication Title
Physical Review A - Atomic, Molecular, and Optical Physics
Recommended Citation
Walter, C.,
Gibson, N.,
Li, Y.,
Matyas, D.,
Alton, R.,
Lou, S.,
Field, R.,
Hanstorp, D.,
Pan, L.,
&
Beck, D.
(2011).
Experimental and theoretical study of bound and quasibound states of Ce < sup> - .
Physical Review A - Atomic, Molecular, and Optical Physics,
84(3).
http://doi.org/10.1103/PhysRevA.84.032514
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/9973