"Correlation of the chromatographic eluting strength of solvents with s" by Dean C. Luehrs, David J. Chesney et al.
 

Correlation of the chromatographic eluting strength of solvents with solvent polarity and polarizability parameters

Document Type

Article

Publication Date

1-1-1991

Abstract

The Snyder P' measure of solvent eluting strength In bonded- phase chromatography (BPC) correlates well with the π* and δ solvatochromie parameters with no dependence on either the α hydrogen bond donor strength parameter, the molar volume, or the β hydrogen bond acceptor strength parameter. Furthermore, the correlation of P' with π* and δ is much better than the correlation of P' with ENR (energy of the electronic transition of Nile Red) which had been proposed as a measure of solvent eluting strength in BPC. © 1991, Oxford University Press. All rights reserved.

Publication Title

Journal of Chromatographic Science

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