Electron affinities of states of Sc and Cu
Document Type
Article
Publication Date
3-12-1987
Department
Department of Physics
Abstract
With this work, we begin our treatment of the transition metal electron affinities. A procedure, REDUCE, for reducing the number of parental couplings per configuration present in the first order wave function from as many as 100 to only a few is introduced. Progress toward a comprehensive relativistic‐correlation theory is discussed. Several states in Sc− were examined but none were found to be bound. Two new bound states were obtained for Cu−: 3d9 4s 4p25D and 3d8 4s 4P37F0, with electron affinities 0.109 and 1.052 eV, respectively.
Publication Title
International Journal of Quantum Chemistry
Recommended Citation
Beck, D.,
Cai, Z.,
&
Aspromallis, G.
(1987).
Electron affinities of states of Sc and Cu.
International Journal of Quantum Chemistry,
32(21 S), 457-468.
http://doi.org/10.1002/qua.560320744
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/3904
Publisher's Statement
Copyright © 1987 John Wiley & Sons, Inc. Publisher’s version of record: https://doi.org/10.1002/qua.560320744