[NiL1]3[Cr(CN)6]2·18H2O [L1 = 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane]: a two-dimensional bimetallic assembly exhibiting antiferromagnetic ordering and metamagnetic behavior
Document Type
Article
Publication Date
5-16-2001
Department
Department of Chemistry
Abstract
Reaction of K3[Cr(CN)6] with a square-planar macrocyclic Ni(II) complex leads to a 2D honeycomb-like layered complex with novel hydrogen-bonding linkages in the honeycomb. Magnetic studies reveal that the complex displays a long range antiferromagnetic ordering with TN = 12.6 K at low field, and metamagnetic behavior originating from intralayer ferromagnetic and interlayer antiferromagnetic interactions.
Publication Title
New Journal of Chemistry
Recommended Citation
Xiang, H.,
Gao, S.,
Lu, T.,
Luck, R.,
Mao, Z.,
Chen, X.,
&
Ji, L.
(2001).
[NiL1]3[Cr(CN)6]2·18H2O [L1 = 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane]: a two-dimensional bimetallic assembly exhibiting antiferromagnetic ordering and metamagnetic behavior.
New Journal of Chemistry(6), 875-878.
http://doi.org/10.1039/B101778K
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/16553