Unprecedentedly high efficiency for photocatalytic conversion of methane to methanol over Au-Pd/TiO2-what is the role of each component in the system?

Document Type

Article

Publication Date

3-31-2021

Department

Department of Materials Science and Engineering

Abstract

Direct and highly efficient conversion of methane to methanol under mild conditions still remains a great challenge. Here, we report that Au-Pd/TiO2 could directly catalyze the conversion of methane to methanol with an unprecedentedly high methanol yield of 12.6 mmol gcat-1 in a one-hour photocatalytic reaction in the presence of oxygen and water. Such an impressive efficiency is contributed by several factors, including the affinity between Au-Pd nanoparticles and intermediate species, the photothermal effect induced by visible light absorption of Au-Pd nanoparticles, the employment of O2 as a mild oxidant, and the effective dissolution of methanol in water. More importantly, for the first time, thermo-photo catalysis is demonstrated by the distinct roles of light. Namely, UV light is absorbed by TiO2 to excite charge carriers, while visible light is absorbed by Au-Pd nanoparticles to increase the temperature of the catalyst, which further enhances the driving force of corresponding redox reactions. These results not only provide a valuable guide for designing a photocatalytic system to realize highly efficient production of methanol, but also, highlight the great promise of thermo-photo catalysis.

Publication Title

Journal of Materials Chemistry A

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