The first dinuclear cobalt complex bridged by acetyl-amidate ligands: Di-μ-acetyl-amido-κ < sup> 2 O:N;κ < sup> 2 N:O-di-μ-hydroxido-κ < sup> 4 O:O-bis-[bis-(pyridine-κN) cobalt(III)] bis-(perchlorate) acetonitrile disolvate
Document Type
Article
Publication Date
8-1-2012
Abstract
The title compound, [Co2(C2H4NO) 2(OH)2(C5H5N)4](ClO 4)2·2C2H3N, consists of two octa-hedral CoIII centers arranged around an inversion point in which two cis hydroxide and two trans acetyl-amidate ligands link the two centers together, forming a dimeric cationic complex. Each CoIII center has two cis pyridine ligands which coordinate in the same plane as the cis hydroxide ligands. Two acetonitrile solvent mol-ecules and two perchlorate anions are hydrogen bonded to the H atoms on the bridging hydroxide and acetyl-amidate (N atom) ligands, respectively. © 2012 International Union of Crystallography.
Publication Title
Acta Crystallographica Section C: Crystal Structure Communications
Recommended Citation
Maass, J.,
Luck, R.,
&
Zeller, M.
(2012).
The first dinuclear cobalt complex bridged by acetyl-amidate ligands: Di-μ-acetyl-amido-κ < sup> 2 O:N;κ < sup> 2 N:O-di-μ-hydroxido-κ < sup> 4 O:O-bis-[bis-(pyridine-κN) cobalt(III)] bis-(perchlorate) acetonitrile disolvate.
Acta Crystallographica Section C: Crystal Structure Communications,
68(8).
http://doi.org/10.1107/S0108270112031964
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/10163