Elastic properties of Mg < inf> x Ti < inf> 1-x B < inf> 2 (07FTYJO first-principles calculations

Document Type

Article

Publication Date

3-25-2011

Abstract

The elastic properties, including elastic constants, bulk, and shear moduli, and anisotropic index of hexagonal MgxTi1-xB 2 (0 ≤ x ≤ 1) are obtained using a first-principles density-functional-theory method. A difference in chemical bonding occurs between Ti-rich and Mg-rich diborides, leading to significantly different elastic properties: a small elastic anisotropy with relatively large bulk and shear moduli for Ti-rich diborides with x < 0.25, and a large elastic anisotropy and relatively small bulk and shear moduli for Mg-rich diborides with x > 0.25. The calculated results reveal a dominant role of the interplanar metal-metal bonds in predicting the extent of shear elastic anisotropy in MgxTi1-xB2 (0 ≤ x ≤ 1). © 2011 American Physical Society.

Publication Title

Physical Review B - Condensed Matter and Materials Physics

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