Date of Award

2024

Document Type

Open Access Master's Thesis

Degree Name

Master of Science in Materials Science and Engineering (MS)

Administrative Home Department

Department of Materials Science and Engineering

Advisor 1

Paul Sanders

Committee Member 1

Stephen Kampe

Committee Member 2

Walt Milligan

Abstract

Recent sustainability efforts have reduced CO2 emissions from electricity generation by increasing operating temperatures and pressures in advanced ultra-supercritical (A-USC) power plants. However, the extreme operating conditions in these A-USC power plants require new high temperature materials. The recent study of nickel-based high-entropy alloys (HEA) represents the latest approach to meet the specifications for A-USC operations. A CALculation PHase Diagram (CALPHAD) driven Bayesian optimization method was used to design the composition of alloys composed of NiCrCoFe with V or W, which were fabricated via wire-based additive manufacturing to enable high throughput development. Although the alloy was designed to minimize solidification cracking, cracking was still observed in the alloy. This research seeks to examine the cracking mechanisms in HEA produced with wire additive manufacturing.

Included in

Metallurgy Commons

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