Off-campus Michigan Tech users: To download campus access theses or dissertations, please use the following button to log in with your Michigan Tech ID and password: log in to proxy server
Non-Michigan Tech users: Please talk to your librarian about requesting this thesis or dissertation through interlibrary loan.
Date of Award
Campus Access Dissertation
Doctor of Philosophy in Environmental Engineering (PhD)
Administrative Home Department
Department of Materials Science and Engineering
Yun Hang Hu
Committee Member 1
Committee Member 2
Committee Member 3
It is generally recognized that H2O adsorption on a porous material would inhibit H2 adsorption. However, Chapter 3 reports that stable H2O-functionalized ZIF-8(a representative MOF), which was obtained by the simple water treatment of ZIF-8 at ambient temperature, can increase its H2 adsorption heat from 5.2 to 10.1 kJ/mol. As a result, the reversible H2 capacity at ambient temperature increased by 77%.
A suitable isotherm equation for C2H2 adsorption on various MOFs has not been found. Chapter 4 demonstrates that Dubinin-Astakhov equation can be exploited as a general isotherm model to depict C2H2 adsorption on MOF-5, ZIF-8, HKUST-1, and MIL-53. Furthermore, it was found that the adsorption of C2H2 on the defected MIL-53 is stronger than that on MIL-53 without defection, reflected by adsorption-heat increase from 19.3 to 25.1 kJ/mol.
Chapter 5 finds that the adsorption of CO2 on the defected ZIF-8 is stronger than that on ZIF-8 without defection, reflected by initial adsorption-heat increase from 16.0 to 22.8 kJ/mol. As a result, the specific reversible CO2 capacity per surface area increased with increasing defects.
A novel strategy was developed to enhance the hydrophilicity on the external surface of ZIF-8 without reducing or blocking the internal pores in Chapter 6. A simple ball-milling approach combined with water treatment results in a significantly higher cell viability without compromising its hydroxyurea loading and release capacity.
It’s a challenge to build a memristor with odd-symmetric I–V features. In Chapter 7, a novel strategy, in which two same asymmetric switch components can be combined as a symmetric device, is reported to create an odd-symmetric memristor. Furthermore, with this strategy, the surface-sulphurization was performed on both sides of a Ag foil, leading to a Ag2S/Ag/Ag2S odd-symmetric memristor consisting of two asymmetric Ag2S/Ag memristive switches.
Chapter 8 demonstrate that 2H phase of bulk MoS2 possessed an ohmic feature, whereas 1T phase of exfoliated MoS2 nanosheets exhibited a unique memristive behaviour due to voltage-dependent resistance change. Furthermore, an ideal odd-symmetric memristor with odd-symmetric I–V characteristics was successfully fabricated by the 1T phase MoS2 nanosheets via combining two asymmetric switches anti-serially.
Cheng, Peifu, "Materials for Energy, Drug, and Information Storage", Campus Access Dissertation, Michigan Technological University, 2015.