Title

Expanding molecular transition metal cubane clusters of the form [M < inf> 4 (μ < inf> 3 -O) < inf> 4 ] < sup> 12+ : Syntheses, spectroscopic and structural characterizations of molecules M < inf> 4 (μ < inf> 3 -O) < inf> 4 (O < inf> 2 P(Bn) < inf> 2 ) < inf> 4 (O < inf> 4 ), M = V < sup> V and W < sup> V

Document Type

Article

Publication Date

11-21-2011

Abstract

Oxidizing the trimer V3(μ3-O)(O 2)(μ2-O2P(Bn)2) 6(H2O) in the presence of excess tBuOOH results in V4(μ3-O)4(μ2-O 2P(Bn)2)4(O4) and heating W(CO) 6 and bis(benzyl)phosphinic acid in 1:1 EtOH/THF at 120 °C produces W4(μ3-O)4(μ2-O 2P(Bn)2)4(O4). © 2011 The Royal Society of Chemistry.

Publication Title

Dalton Transactions

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