Allylic alcohol isomerization and mechanistic considerations with CH < inf> 3 ReO < inf> 3
Document Type
Article
Publication Date
9-13-2004
Abstract
A mechanism for the isomerization of allylic alcohols by CH 3ReO 3 has been constructed on the basis of 18O isotopic studies and involves exchange between the alcohol and metal-bonded O atoms, in contrast to a previously published mechanism, which involved the 1,3-transposition of the O atom on the alcohol. Our method of analysis does not directly rule out this latter mechanism.
Publication Title
Organometallics
Recommended Citation
Wang, G.,
Jimtaisong, A.,
&
Luck, R.
(2004).
Allylic alcohol isomerization and mechanistic considerations with CH < inf> 3 ReO < inf> 3 .
Organometallics,
23(19), 4522-4525.
http://doi.org/10.1021/om049669v
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/8199