Title

Dimethyl sulfoxide complexes of silver(I) in solution

Document Type

Article

Publication Date

1-1-1971

Abstract

The stability constants of dimethyl sulforxide complexes of silver (I) in methanol, 2-butanol, acetone, sulfolane, 70% dioxane, and nitroethane were determined by potentiometric titrations. No dimethyl sulfoxide complexes of silver(I) are formed in water. The stability of dimethyl sulfoxide complexes of silver(I) in a particular solvent depends upon the formal reduction potential of silver(I) in the solvent and the strength of the hydrogen bonding interaction between dimethyl sulfoxide and the solvent. © 1971 Elsevier Sequoia S.A., Lausanne.

Publication Title

Journal of Electroanalytical Chemistry

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