Sooting characteristics of surrogates for jet fuels
Currently, modeling the combustion of aviation fuels, such as JP-8 and JetA, is not feasible due to the complexity and compositional variation of these practical fuels. Surrogate fuel mixtures, composed of a few pure hydrocarbon compounds, are a key step toward modeling the combustion of practical aviation fuels. For the surrogate to simulate the practical fuel, the composition must be designed to reproduce certain pre-designated chemical parameters such as sooting tendency, H/C ratio, autoignition, as well as physical parameters such as boiling range and density. In this study, we focused only on the sooting characteristics based on the Threshold Soot Index (TSI). New measurements of TSI values derived from the smoke point along with other sooting tendency data from the literature have been combined to develop a set of recommended TSI values for pure compounds used to make surrogate mixtures. When formulating the surrogate fuel mixtures, the TSI values of the components are used to predict the TSI of the mixture. To verify the empirical mixture rule for TSI, the TSI values of several binary mixtures of candidate surrogate components were measured. Binary mixtures were also used to derive a TSI for iso-cetane, which had not previously been measured, and to verify the TSI for 1-methylnaphthalene, which had a low smoke point and large relative uncertainty as a pure compound. Lastly, surrogate mixtures containing three components were tested to see how well the measured TSI values matched the predicted values, and to demonstrate that a target value for TSI can be maintained using various components, while also holding the H/C ratio constant. © 2010 The Combustion Institute.
Combustion and Flame
Sooting characteristics of surrogates for jet fuels.
Combustion and Flame,
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