Correlation of the gibbs free energy of transfer of fluoride ion from water to other solvents with solvent actidity and polarity parameters
Document Type
Article
Publication Date
2-1990
Department
Department of Chemistry; Department of Chemical Engineering; Department of Mathematical Sciences
Abstract
Linear free energy relationships between the free energy of transfer of fluoride ion from water to other solvents or solvent mixtures and each of several parameters describing the acidity of the solvent were found. The correlation is about of the same quality for the A parameter of Swain or the acceptor number, AN, and almost as good for the α parameter of Taft. The correlation was somewhat poorer with the ET(30) parameter.
Publication Title
Journal of Solution Chemistry
Recommended Citation
Luehrs, D.,
&
Godbole, K.
(1990).
Correlation of the gibbs free energy of transfer of fluoride ion from water to other solvents with solvent actidity and polarity parameters.
Journal of Solution Chemistry,
19(2), 187-192.
http://doi.org/10.1007/BF00646612
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/4262