An alternative interpretation of the chemical shift of the water proton in aqueous tetraalkylammonium halide solutions at various temperatures
Document Type
Article
Publication Date
4-1978
Department
Department of Chemistry; Department of Chemical Engineering
Abstract
An alternative explanation of the behavior of proton magnetic resonance chemical shifts of the water proton in aqueous tetraalkylammonium salt solutions is presented. It involves independent ion-solvent interactions and rapid exchange on the NMR time scale with the bulk water. Our explanation fits the known data and clearly shows why the observed chemical shift is linear with molality at low concentrations.
Publication Title
Journal of Solution Chemistry
Recommended Citation
Kreishman, G.,
&
Leifer, L.
(1978).
An alternative interpretation of the chemical shift of the water proton in aqueous tetraalkylammonium halide solutions at various temperatures.
Journal of Solution Chemistry,
7(4), 239-243.
http://doi.org/10.1007/BF00644271
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/4261