Enthalpies of vaporization of some highly branched hydrocarbons
Document Type
Article
Publication Date
1-1-1995
Department
Department of Chemistry
Abstract
Measurements of the molar enthalpy of vaporization ΔvapHmat the temperatureT= 298.15 K are reported for 14 liquids and 6 solids each containing one or more quaternary carbon atoms, by the methods of transpiration, head-space analysis, or gas chromatography. The results are compared with literature values and with estimates based on a simple two-parameter equation developed previously for hydrocarbons. A relation between the solvent-accessible surface areaAand the value of ΔvapHmhas been observed for hydrocarbons containing quaternary centers. Measurements of the molar enthalpies of sublimation ΔsubHmare also reported for two more solids atT= 293 K or atT= 298.15 K.
Publication Title
The Journal of Chemical Thermodynamics
Recommended Citation
Chickos, J.,
Hesse, D.,
Hosseini, S.,
Liebman, J.,
David Mendenhall, G.,
Verevkin, S.,
Rakus, K.,
Beckhaus, H.,
&
Rüchardt, C.
(1995).
Enthalpies of vaporization of some highly branched hydrocarbons.
The Journal of Chemical Thermodynamics,
27(6), 693-705.
http://doi.org/10.1006/jcht.1995.0071
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/3958