Title
The structure of some methyl and benzyl malonate derivatives of pyrimidine
Document Type
Article
Publication Date
1-1-1980
Abstract
Reaction of 2,4,6‐trichloropyrimidine with sodium dibenzylmalonate in p‐dioxane gave 4,6‐dichloro‐2‐(dibenzylmalonyl)pyrimidine, while reaction of 2,4,6‐trichloropyrimidine with sodium dimethylmalonate yielded both 4,6‐dichloro‐2‐(dimethylmalonyl)pyrimidine and 2,2‐bis‐(4,6‐dichloropyrimidin‐2‐yl)dimethylmalonate. Structural studies using nmr, ir and uv spectroscopy indicate that for the former two compounds in basic solvent, an equilibrium exists between the keto forms and resonance‐stabilized enolate ions. Copyright © 1980 Journal of Heterocyclic Chemistry
Publication Title
Journal of Heterocyclic Chemistry
Recommended Citation
Reynolds, G.,
&
Fenwick, M.
(1980).
The structure of some methyl and benzyl malonate derivatives of pyrimidine.
Journal of Heterocyclic Chemistry,
17(3), 589-592.
http://doi.org/10.1002/jhet.5570170334
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/3742