The structure of some methyl and benzyl malonate derivatives of pyrimidine
Document Type
Article
Publication Date
1-1-1980
Department
Department of Chemistry; Department of Chemical Engineering
Abstract
Reaction of 2,4,6‐trichloropyrimidine with sodium dibenzylmalonate in p‐dioxane gave 4,6‐dichloro‐2‐(dibenzylmalonyl)pyrimidine, while reaction of 2,4,6‐trichloropyrimidine with sodium dimethylmalonate yielded both 4,6‐dichloro‐2‐(dimethylmalonyl)pyrimidine and 2,2‐bis‐(4,6‐dichloropyrimidin‐2‐yl)dimethylmalonate. Structural studies using nmr, ir and uv spectroscopy indicate that for the former two compounds in basic solvent, an equilibrium exists between the keto forms and resonance‐stabilized enolate ions.
Publication Title
Journal of Heterocyclic Chemistry
Recommended Citation
Reynolds, G.,
&
Fenwick, M.
(1980).
The structure of some methyl and benzyl malonate derivatives of pyrimidine.
Journal of Heterocyclic Chemistry,
17(3), 589-592.
http://doi.org/10.1002/jhet.5570170334
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/3742
Publisher's Statement
Copyright © 1980 Journal of Heterocyclic Chemistry. Publisher’s version of record: https://doi.org/10.1002/jhet.5570170334