Title
A two-dimensional, hydrogen-bond-cross-linked molybdenum(VI) network polymer with catalytic activity
Document Type
Article
Publication Date
6-27-2007
Abstract
The new hybrid inorganic-organic polymer [MoO2Cl 2(H2O)2]·(H2dipy-pra)Cl 2 (1), where dipy-pra = 1,3-bis(4-pyridyl)propane, has been synthesized and crystallographically characterized. MoO2Cl 2(H2O)2 and the [H2dipy-pra] 2+ cation are cross-linked by Mo-H2O⋯O and H 2dipy-pra⋯Cl hydrogen bonds to form a two-dimensional layer structure. Complex 1 is an efficient catalyst, with H2O2 as the oxygen-source oxidant and NaHCO3 as the cocatalyst, in the epoxidation of olefinic compounds under ambient conditions. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
Publication Title
European Journal of Inorganic Chemistry
Recommended Citation
Luan, Y.,
Wang, G.,
Luck, R.,
&
Yang, M.
(2007).
A two-dimensional, hydrogen-bond-cross-linked molybdenum(VI) network polymer with catalytic activity.
European Journal of Inorganic Chemistry(9), 1215-1218.
http://doi.org/10.1002/ejic.200601054
Retrieved from: https://digitalcommons.mtu.edu/michigantech-p/3598