Theoretical study of small clusters of indium oxide: InO, In2O, InO2, In2O2
The structural, vibrational and electronic properties of small clusters of indium oxide (InmOn; m; n = 1, 2) in the neutral and the ionic state are studied using ﬁrst-principles method based on density functional theory. The linear structures are preferred over all the other possible structures for the neutral InO clusters. The structural deformations and the instability in InO, In2O; InO2 and In2O2 are relatively higher when an electron is removed than the case when an electron is added to it. In2O, with negative electron afﬁnity, is predicted to be highly unstable. The calculated results suggest that the neutral InO clusters are likely to become unstable when the metal to oxygen ratio is larger than unity.
Journal of Molecular Structure: THEOCHEM
Theoretical study of small clusters of indium oxide: InO, In2O, InO2, In2O2.
Journal of Molecular Structure: THEOCHEM,
Retrieved from: https://digitalcommons.mtu.edu/data-science-fp/23
© 2010 Elsevier Ltd. Publisher's version of record: http://dx.doi.org/10.1016/j.theochem.2010.02.016